Characteristics of TiO2 Compact Layer prepared for DSSC application

Nicholas Musila, Mathew Munji, Justus Simiyu, Eric Masika, Raphael Nyenge, Miriam Kineene

Characteristics of TiO2 Compact Layer prepared for DSSC application

Číslo: 10/2018
Periodikum: Path of Science
DOI: 10.22178/pos.39-6

Klíčová slova: Raman spectroscopy; compact layer; dye sensitized solar cell; morphology index; tetragonal crystalline structure; specific surface area; spray pyrolysis

Pro získání musíte mít účet v Citace PRO.

Přečíst po přihlášení

Anotace: Dye-sensitized solar cells (DSSCs) offer an economically reliable and suitable alternative in moderating the challenges presented by the existing convectional photovoltaic cells. However, the efficiency of dye-sensitized solar cells has remained relatively low. For this reason, this research was aimed at studying the characteristics of TiO2 compact layer that can be applied in DSSCs as a way of improving efficiency. To achieve this, TiO2 compact layer was deposited on a conductive glass substrate by using Holmarc’s Spray Pyrolysis system, using Ultrasonic Spray Head and spraying in the vertical geometry. X-ray Diffraction studies revealed that TiO2 compact layer was of anatase phase and had tetragonal crystalline structure. Raman spectroscopy showed that the most intense peak appeared at 142 cm-1 due to the external vibration of the anatase structure. Hall Effect studies revealed that TiO2 compact layer has a high density of charge carriers’ value of 1.25 × 1019 cm-3 hence it can be used in DSSC applications.