A sustainable approach to improvement of corrosion protection coatings for steel structures

Two base polymer coatings (vinyl and coal-tar epoxy) were considered. The following types and dosages of biobased ion exchangers were evaluated in these coatings: (i) strong-base ion exchange cellulose in OH, PO4, SiO3, BO3, NO2, SO4 and NO3 forms at 1% by weight of resin; (ii) weak-acid starch citrate ion exchanger in H form at 1 wt.%; and (iii) strong-base ion exchange cellulose in OH form at 2 wt.%. In addition, a strong-base ion exchange resin in OH form was considered at 1 and 2 wt.% as control. Different coating formulations were evaluated based on the outcomes of salt-fog corrosion, moisture resistance, pull-off strength, and abrasion resistance tests. The introduction of certain biobased ion exchangers in protective coatings was found to be an effective means of achieving improved levels of corrosion resistance, adhesion capacity, moisture stability and abrasion resistance.